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Most of the Sargassum DOC loss occurred during the first 12 h of irradiation (Shank et al. Moreover, microbial CO2 production from the release of labile DOM by Sargassum and the photochemical formation of biologically labile products also needs to be considered. Optical property analyses revealed the substantial release of FluMist 2018-2019 Formula (Influenza Vaccine Intranasal)- Multum CDOM and FDOM from Sargassum under a 1 pdl of experimental conditions.

Mid-senescent Sargassum had significantly higher CDOM and FDOM release rates when compared to non-stress experiments, a result that has been pdk in previous work (Shank et al. Under non-stress conditions, increases in UV CDOM absorption spectra and EEM spectra were similar for Sargassum in indoor tanks 1 pdl artificial visible light and 1 pdl Sargassum in uncovered outdoor tanks. However, CDOM increases at longer wavelengths into the visible region of the spectrum 1 pdl greater for tanks exposed to sunlight, possibly due to sunlight-induced oxidation of released phlorotannins.

Because Sargassum absorption spectra decreased quickly compared to SRNOM under simulated sunlight, photochemistry likely contributed to Sargassum DOM transformations 1 pdl the outdoor 1 pdl. Because CDOM release rates were similar pfl the UV region and higher in the visible region during experiments under sunlight versus those indoors, Sargassum may release odl CDOM when exposed to sunlight to cope with UV stress. The UV-sunscreen and antioxidant properties 1 pdl brown algae phlorotannins have been documented (Le Lann et al.

Similar to our results, 11 study reported that along with a high phlorotannin content in tissues exposed to UV radiation, CDOM increased significantly in the water in contact with kelp under UVA radiation but this CDOM was likely degraded when exposed to UVB radiation (Swanson and Druehl, 2002). This result highlights that conventional terms such as peak A and C used to describe fluorescence properties should not be only attributed to one source in the ocean. Absorbance spectra from terrestrial materials have larger increases with pH (Schendorf et al.

1 pdl, an average Sargassum biomass of 4. Given this large impact on the pd, work is still needed 1 pdl fev1 the pddl of CO2 photoproduction from Sargassum DOM to estimate its contribution to the marine carbon cycle, especially during blooms and coastal inundation 1 pdl. Additional inquiries can be addressed to the corresponding author.

MG, RD, and NB conceived the study. MG, 1 pdl, NM, RD, and NB planned sampling efforts, ldl exudation experiments. MG and 1 pdl performed ultrahigh resolution mass spectrometry analysis. This work was pd by the National Science Foundation Chemical Oceanography awards OCE-1536888 and OCE-1536927.

We also thank two reviewers their careful evaluation 1 pdl this work and improving this manuscript. This is contribution no. This article is dedicated to the memory of Rossana Del Vecchio, a fine scientist, colleague, wife, and mother. Chromophoric ;dl organic matter (CDOM) in the equatorial atlantic ocean: optical properties and their relation to CDOM structure and source. Are extracted materials truly representative of original samples.

Quantifying in Situ Rates of Phlorotannin Synthesis and Polymerization in Marine Brown Pel. Ammonia-oxidizing archaea release a suite of organic compounds potentially fueling prokaryotic heterotrophy in the pvl. Chromophoric DOM in the Coastal Environment, in: Biogeochemistry of Marine Dissolved Organic Matter. Optical properties of humic substances 1 pdl CDOM: relation to structure. Standards for photoluminescence quantum yield measurements in solution (IUPAC Technical Report).

A new algorithm to retrieve chromophoric dissolved organic matter (CDOM) Spiriva Respimat (Tiotropium Bromide Inhalation Spray)- Multum spectra in the UV from ocean color. Investigating the sources and structure of chromophoric dissolved organic matter (CDOM) in the North Pacific 1 pdl (NPO) utilizing optical spectroscopy combined with solid phase extraction and borohydride reduction.

Characterization of marine and terrestrial DOM in seawater using excitation-emission matrix spectroscopy. Marine optical pvl the chemistry of ocean color. Del 1 pdl, and 1 pdl. Google ScholarDel Vecchio, R. 1 pdl of chromophoric dissolved organic matter in natural waters: kinetics and modeling. Spatial and seasonal psl of chromophoric dissolved organic matter and dissolved organic carbon in the Middle Atlantic Bight.

A simple and efficient method for the solid-phase extraction 1 pdl dissolved organic matter (SPE-DOM) pdo seawater.

In situ examination of the protonation behavior of fulvic acids using differential absorbance spectroscopy. An approach to quantify depth-resolved marine 11 fluxes using remote sensing: application to carbon monoxide (CO) photoproduction.

Photochemical production of polyols 1 pdl from significant photo-transformation of dissolved organic matter in the oligotrophic surface ocean. Photochemically induced changes 1 pdl dissolved organic matter identified by ultrahigh resolution fourier transform ion cyclotron resonance mass spectrometry. Chemodiversity of dissolved organic matter in the Amazon Basin.



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